In this review, we summarize the application of molybdenum-based materials in various kinds of aqueous batteries, which begins with LIBs and SIBs and then extends to multivalent ion batteries such as ZIBs and AIBs. Some new energy storage systems, such as ammonium-ion batteries, are also mentioned.
Compared with typical carbon-based materials, molybdenum-based materials own a much higher specific capacitance, taking advantages of their multiple oxidation states that are in favor of fast charge storage [ 9, 10 ], which are considered as promising electrode candidates for aqueous batteries.
Provided by the Springer Nature SharedIt content-sharing initiative A simple and effective carbon-free strategy is carried out to prepare mixed molybdenum oxides as an advanced anode material for lithium-ion batteries.
Ji, W. et al. Partially nitrided molybdenum trioxide with promoted performance as an anode material for lithium-ion batteries. Journal of Materials Chemistry A 2, 699 (2014). Zhao, G., Zhang, N. & Sun, K. Electrochemical preparation of porous MoO3 film with a high rate performance as anode for lithium ion batteries.
Among existing materials, molybdenum oxides containing MoO 3 and MoO 2, as well as their composites, are very fascinating contenders for competent energy-storage devices because of their exceptional physicochemical properties, such as thermal stability, high theoretical capability, and mechanical strength.
Conclusion and perspectives We have comprehensively summarized the latest development of molybdenum oxides and molybdenum sulfides for aqueous rechargeable batteries. At present, the application of molybdenum-based materials in aqueous batteries is still in its infancy, and there are only few works reported recently.
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